NMR and Macromolecules: Sequence, Dynamic, and Domain Structure (ACS Symposium Series)

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Galembeck, F. Herzog Cardoso, A.

KIT Polymer Science - Publikationen

Moita Neto, J. Product characterization was done by centrifugation in density gradients coupled to scattered light scanning photometry of the centrifugation tubes. IR and NMR spectra were obtained from bulk polymer as well as from isopycnic centrifugation fractions. Spectra of latex isopycnic fractions do also show significant differences arising from their monomer chemical compositions, but isopycnic centrifugation and spectral data do not reveal any correlation between particle density and monomer composition.

Isopycnic centrifugation can thus solve two problems on latex characterization: first, it is a high-resolution preparative technique, unmatched by any other separation method. Second, it yields latex particle fingerprints, which are dependent on particle chemical characteristics, rather than on particle diameters.

3 editions of this work

Colloid And Polymer Science. Napper, D. Pergamon Press, London. Klein, A.

Publikationen der Arbeitsgruppe / Publications research group Prof. Wilhelm

Poehlein, G. Blackley, D. Daniels, E. Van Doremaele, G.

Nmr and Macromolecules: Sequence, Dynamic, and Domain Structure (Acs Symposium Series)

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Schmidt-Rohr Group Publications

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